![]() ![]() You can help support Brick Fanatics’ work by using our affiliate links.Christopher Ruge originally submitted this model of the International Space Station to the LEGO Ideas Platform back in 2017, and despite reaching 10000 supporters, it was not successful in the initial review. This product was provided for review by the LEGO Group.Ģ1321 International Space Station will be available from February 1 at. Be sure to not overlook this one, IDEAS sets tend not to hang around too long… ![]() It may not be one for play (every time you pick it up you’ll move one of the poseable solar panels dotted all around it), nor one for those suffering from NASA fatigue in what has been a Space-heavy period for the LEGO Group, but as a detailed and accurate LEGO tribute to one of man’s most important scientific ventures of the last two decades, there’s nothing better. At £65 for 864 pieces, it also offers more than decent value for money. It captures the intricate nature of its subject to create an engaging display piece that on every glance reveals something new. Trio of LEGO designers) is passionate about.Ģ1321 International Space Station is a set that for all that it includes and achieves is a perfect addition to any LEGO NASA fan’s growing collection. From even the design of the display stand that houses everything,Ģ1321 is smart and celebrates everything that its fan designer (followed by the (how many years have we had high quality stickers now?), helps elevate theīuild experience and consistency of the final model just that little bitįurther. Whilst there are also two astronaut microfigures (three if you include the spare) identical to the trio included in 2017’s 21309 Apollo 11 Saturn V, there’s no comparable scale between these two sets – the shuttle’s length would come in at half the height of the rocket, if they were built to the same scale.Įverything is printed, which, although a small thing in 2020 Three cargo ships are also included, as well as a mini space shuttle that most accurately reflects the scale that this model has been designed at – deliberately the same as the shuttle included in 2017’s IDEAS set, 21312 Women of NASA. ![]() It’s a set that is most comparable to the Architecture line, both for the display model that it creates as a final product, the level of detail that it explores in its construction, and the little techniques thrown in there that are as subtle as they are smart. This is a set based on a submission that fan designer Christoph Ruge admits he spent more than three years fine-tuning, and it shows. But, its strength is in its intricacy, which is remarkably achieved in what is still a very solid structure. It is not a set that will immediately jump out at you whilst on display, in comparison to other sets across the LEGO Group’s current roster, or indeed in comparison to some of the more recent releases within the IDEAS theme. Importantly then, 21321 International Space Station packs in the detail, embracing the creative potential of microscale to capture not only the many modules that make up the station, but also their complex shaping and directional changes. Years of continuous occupation within it, since long term residents first movedīut, relevance and overall theme continuity alone do not make a great LEGO IDEAS set. Special anniversary for the International Space Station, as this year marks 20 Released to signify IDEAS’ 10-year anniversary (reached inĢ018, before the review and vote in 2019), 21321’s arrival in 2020 also hits a
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12/15/2023 0 Comments Nier automata 2b funny![]()
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If you have another branch you’ve worked at that you want to push to remote, you’ll still use the git push command, but in a slightly different way.Īs a reminder, to create a new branch, you run git branch branch-name. That’s how you push the main branch for the first time. If you have not configured Git to use a credential helper, you will be asked for your GitHub username and PAT (personal access token): Initially, it was “master”, so I ran git branch -M main to change it. (“main” is the name of that branch for me). To finally push the repo, run git push -u origin To confirm the remote has been added, run git remote -v: To push the main repo, you first have to add the remote server to Git by running git remote add. git commit -m ‘commit message’ to save the changes you made to those files.to add all your files that the local repository git init for initializing a local repository.Before you attempt to push to remote, make sure you’ve executed these commands: If you want to push the main branch to remote, it’s possible you’re pushing for the first time. I’m going to show you everything from scratch. You might even have pushed your main branch and want to push another branch. ![]() It doesn’t matter whether you are yet to push at all. In this article, I’ll show you how to push a local git branch to a remote server. In the long run, you'll have to push those independent branches to a remote server. And if you work in a team, different developers might have unique branches they work on. Git branches let you add new features without tampering with the live version of your projects. 12/15/2023 0 Comments Driverpack solution 2014 iso![]() ![]() SPP is a systems software and firmware solution delivered as a single ISO file. DriverPack Solution serves the choice, which automatically sorts out and requires user permission to update all devices with latest drivers. Overview on HPE Smart Update Manager SUM is a tool for firmware, driver. DriverPack Solution is the most popular program that makes the job of finding and automatically installing drivers a pleasure. driverpack solution 14 iso at UpdateStar More DriverPack Solution 17.11.16 DriverPack Solution - Freeware - DriverPack Solution is the most popular program that makes the job of finding and automatically installing drivers a pleasure.DriverPack Solution simplifies the process of reinstalling Windows on any computer. 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Within 2-3 minutes all missing and outdated drivers will be sorted out and requiring single click for their most recent version update.īefore updating drivers for a specific device or devices, DriverPack Solution lists them for user to choose which device is left without update which is to be considered. Although there exists many other such application’s including UniBlue Driver Scanner 2015, but DRP 14, because of its quick driver search and update options is preferred choice for professionals. This version has several new options and optimized for all platforms (x86-圆4), and conjointly supports the new software Windows eight.1. CHECK ALSO: FonePaw Screen Recorder 1.10.0ĭriverPack Solution 14 is compatible with all windows OS platforms which makes it a versatile suite for all. Driver Pack Solution 2014 Free Download Full Version Description: DriverPack solution 01-06-2014 Associate updated version of the powerful program that may mechanically install the drivers on your laptop. 12/15/2023 0 Comments Maurices capital one phone numberis an independent information hub that has no affiliation with Maurices Credit Card or with any government, federal or state department, agency, board, office, or commission. Simply send us a message using the contact us form or the comments form below. We will do the leg work for you, completely free. Need additional information for Lost Maurices Credit Card? Need help from us about you Lost Maurices Credit Card? Our team is available to help you promptly. We will confirm and publish the information promptly. We’d appreciate if you find new information about Lost Maurices Credit Card and send it to us. Does Capital One have a 24 hour number? Sign in to 24/7.This website is a completely free website providing Lost Maurices Credit Card information and additional details on your credit card company and other leading lost cards companies. If you need to speak about credit card сustomer service (for servicing of existing accounts only) you need to dial 1-80. You can reach Capital One customer service via 1-87. What is Capital One customer service phone number? name, address) with limited third parties solely for fraud prevention services. This sometimes means sharing your information (e.g. To confirm your identity, we need information from a number of sources. Capital One takes security seriously and fights hard to prevent identity theft, which protects both of us. How did Capital One get your cell phone number? Comenity Phone Numbers and Emails Toll-Free Number: (855) 796-9632 Call customer. Capital One is a well-known financial services company that offers credit cards. What is Capital One customer service phone number? Capital One bank Customer Service Phone Numbers. This site gives access to services offered by Comenity Capital Bank. Bealls Credit Card: Login & Customer Service Phone Number. Capital One Financial Corporation is a bank holding company specialized in facilities, home loans, auto loans, banking services and also in savings products. What is Capital One 800 number? Capital One Customer Service Phone Number : 1-80. While being able to exchange miles for travel statements, booking for upcoming flights, or obtaining new hotel bookings may make them more valuable, in most cases those transactions were easier than redeeming miles. Travel, cash, and Capital One Venture miles can be redeemed on your Capital One Venture account. Frequently Asked Questions How do you contact Capital One? Once you enter your information, you’ll get a summary of your credit card account, including the balance and any upcoming due dates. You’ll be asked to say or type the last 4 digits of your card number and Social Security number. You can pay your Capital One credit card by phone by calling the automated customer service line at (800) 227-4825. Find the nearest maurices to you View our store pages for phone numbers, driving directions, hours and more.You should set up bill payment through Capital One …Ĭapital One Pay By Phone Info – WalletHub The proportion of the losses charged to Maurice S. From within your 360 Checking account, select Pay Bills. was one, and the representatives of the estate of the deceased partner, Maurice S. You can schedule up to three payments … To set up Bill Pay : Sign in to Capital One ®. Make your online payment quickly and easily. Get access to 100M+ contacts on Adapt.io. If you want to send us a cheque, please post it to: Capital One Europe Plc, PO Box 1517, NORTHAMPTON, NN1 9GZ. 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12/15/2023 0 Comments Kerbal space program 2 prtice![]() ![]() Finally, improved contextual information will give players a better idea how to respond to unexpected vehicle failures. For long distance flights, players can now use time warp while accelerating, to remove long waits during interplanetary travel. The time warp system not only includes more zoom levels, but it will also allow the player to pause time while interacting with controls. The sequel will feature massive user experience improvements ranging from enhanced map and maneuver iconography to an all-new flight HUD. Fully-interactive animated tutorials will reveal the secrets of rocketry, while a revamped vehicle assembly interface combines ease of use and powerful new vehicle creation tools. “At its heart, KSP2 is about exploration, discovery, and conquering the force of gravity by adding more boosters.”īuilt from the ground up, Kerbal Space Program 2 will teach the joy of accidentally learning rocket science to a new generation of players while providing unique challenges and innovative capabilities to seasoned Kerbal veterans. “We are so excited to release Kerbal Space Program 2 in Early Access because it will allow Kerbal fans to see for themselves all the amazing progress we’ve made as we reach the final stages of development,” said Nate Simpson, Creative Director at Intercept Games. Fans will also enjoy sailing through beautiful cloudscapes thanks to the new planetary atmosphere system. Blast off from the beautiful Kerbin, explore the pockmarked and breathtaking Mun, see the towering green clouds of Jool, and discover stunning vistas on these remade celestial bodies! All these classic locations have been reimagined, bringing all-new levels of realism and complexity through a terrain system that will provide new challenges when selecting a landing site. At the launch of Early Access, players will be able to travel fully throughout the Kerbolar system. In addition to this greater array of new parts, the game will feature rich environments to explore. Kerbal Space Program 2 will also introduce the ability to customize and paint vehicles, leading to deeper personalization and expression in every build. From this deep parts box, players can craft planes, rockets, rovers, and other creations for their adventures. When the game launches in Early Access, there will be over 350 new and improved parts to build with, including engines, fuel tanks, procedural part systems, and much more. The core experience will be better than ever in Kerbal Space Program 2, as players will have near limitless possibilities with the tools at their disposal to construct advanced spacecrafts and lunar vehicles. 12/15/2023 0 Comments Bricscad help![]() Select an object and press Ctrl + 1 to open the properties palette which lists the properties of the object. Press it again to reset the default AutoCAD interface. Ctrl + 0Ĭlears screen to show only the drawing area and hides palettes and tabs. You can use this keyboard shortcut to save the drawing as a new file, in short, this is the hotkey for “save as” command. You can use this keyboard shortcut to save a drawing file. You can use this shortcut to open a new drawing tab in AutoCAD. In this list, I have included some of the most frequently used and useful keyboard shortcuts Ctrl + N Launch the User Profile Manager from the Windows Start Menu.Keyboard shortcuts or hotkeys are the shortest and quickest way of activating some of the common AutoCAD operations or commands.If the issue disappears when you run with a new profile, then that points to a setting issue in your original profile. When you create a new profile, BricsCAD will automatically run with the program default settings. Rather than trying to determine the problem setting it can often be easier to create a new profile, and run BricsCAD with that. At times these setting can get changed or corrupted leading to unexpected results. If the issue disappears after doing this, it points to a problem with one of the support files in the old folder.īricsCAD has hundreds of settings. The next time you run BricsCAD, it will see that this folder is missing and will recreate the contents using the defaults. Note renaming is preferable to deleting, as it allows you to restore it back again, or retrieve any files you find missing later on. Rename this folder to a different name e.g. In this folder you should see a sub-folder of the same name as your BricsCAD version.In Windows Explorer copy & paste the following into the address bar.Make sure that BricsCAD is not running.From time to time these files can get corrupted, which can lead to issues running BricsCAD. If your Antivirus is doing this, then you will need to whitelist the BricsCAD application.īricsCAD places support files under your roaming windows profile. Some can block BricsCAD from installing properly, or will remove key files BricsCAD requires to run. When installing and running BricsCAD, check that it isn't having issues with your Antivirus application. Bricsys provides MD5 hash codes that allows you to confirm that the downloaded installer is complete. Make sure that you have the latest version of BricsCAD downloaded.First uninstall the current installation. ![]() It also won't prevent LISP from being loaded. Note this isn't a fool proof method as 3rd party applications can employ several means to load. This prevents automatic running of 3rd party applications.
12/15/2023 0 Comments Proxie serverces![]() The HTTP Proxy listens for incoming HTTP requests (Listening Interface and HTTP/S Listening Port) from the clients and then forwards the requests to the relevant HTTP host, based on the URL (HTTP Location) in the incoming HTTP GET request. The HTTP hosts are located in the cloud and the clients are located behind NAT. The figure below illustrates this example where IP Phones (clients) retrieve their configuration and firmware files from remote file servers (Upstream Hosts) and where the device (HTTP Proxy) intermediates between the two. For example, you can use it to intermediate between REST API clients and a REST server.Īnother example is to use the HTTP Proxy to intermediate between IP Phones and remote servers for file download. You can use this for many HTTP-based applications. HTTP Reverse Proxy for managing equipment behind NAT: You can configure the device to function as a Reverse HTTP Proxy server. The device supports the following proxy services: For more information, see Configuring HTTP Directive Sets. You can also configure and apply additional NGINX Directives that do not have any corresponding parameters in the device's Web interface. For example, if you have configured an Upstream Host (discussed later in this section), it is displayed in the NGINX file as "server host:port". Each parameter has its own NGINX Directive notation syntax, which is shown in the nf file. When you then configure the various HTTP Proxy tables, the configuration is reflected in the NGINX configuration file (nf). ![]() When you enable the HTTP Proxy application, the NGINX daemon is launched. This feature integrates the NGINX platform, which is an open source proxy server. The client sends an HTTP GET request specifying the destination (URL), and the device (acting as an HTTP Proxy), forwards it to the host, and vice versa. In this sense, it ensures that the user remains easily traceable, but having a separate dedicated IP address can have its specific benefits.The device can be configured as an HTTP Proxy (or a non-HTTP Proxy) to intermediate between clients (e.g., HTTP requests) and servers (hosts). Instead, they offer the user a single IP address that only they can use. Some services also offer private proxies, but these aren’t private the way a VPN is. Hotels and cafes use them to authenticate users on public Wi-Fi and companies or home users might also set them up to save bandwidth. These proxies can be set up by employers or parents who want to monitor users’ online activity and block access to specific websites. Transparent proxies – These are a different kind of proxy because their users are usually unaware of their existence.Although they can handle all kinds of traffic, they are usually slower than HTTP proxies because they are more popular and often have a higher load. SOCKS Proxies – These proxies are not limited to web traffic but still only work on the application level.If you set up your browser with an HTTP proxy server, all your browser traffic will be rerouted through it. HTTP Proxies – These only cater to web pages.There are three main types of proxy servers: ![]() ![]() However, proxies only work on the application level, meaning it only reroutes the traffic coming from a single app you set your proxy up with. The web proxy server hides your original IP address so that the website sees the IP of the proxy (in some cases, the computers of other proxy users are used for this). Your traffic goes through a middle-man, a remote machine used to connect you to the host server. Proxy servers act as relays between the website you’re visiting and your device. What is a proxy server and how does it work? 12/15/2023 0 Comments Epoxy ring openinReproduced with permission from St John (1993). DGEBA, Scheme 1.4, or following ring-opening of another epoxy group. Alcohol catalysis of the epoxy-ring-opening reaction by amine groups (the -OH may arise from impurities in the resin, the resin itself, e.g. A novel method for stereoselective synthesis of 4 -a- carbon-substituted nucleosides, through epoxidation of 4, 5 - unsaturated nucleosides and SnCU-promoted epoxy ring opening, was. Benzoylation of 240 followed by hydroboration, PCC oxidation, debenzoylation, and alkaline-promoted cyclization directly formed C3-branching 2-deoxyfuranose 242 (O Scheme 63). Alcohol 239 was carried through benzoylation, deketalization, silylation, and ozonolysis, to produce C-branched y-lactone 241. Zinc-mediated Barbier-t) e addition of 238, followed by Luche s procedure obtained a mixture of the homoallylic alcohol diastereomers 239 and 240. The chain propagation reaction mechanism itself remains trimolecular. Positive, neutral or even negative effects of the alcohol additives on the reaction rate are governed by the relationship between these two factors. On one hand, they increase the reaction rate due to an electrophilic assistance for the epoxy ring opening and, on the other, lower the reactivity of the alcoxy anion owing to its solvation and the decrease of its nucleophility. The affinity of these captodative olefins for. The proposed mode of catalysis is represented by the intermediate 87. Analysis of the reaction mixtures revealed the presence of captodative ethylenes (e.g., 85) formed in situ, whieh were shown to be aetive in eatalyzing the reaction. Certain epoxy ethers (e.g., 89) undergo C-1 attack due to anchimeric assistance. Ring-opening is very facile under these conditions, typically proceeding via normal C-2 attack, as exemplified by styrene oxide (86). An interesting alcoholysis of epoxides has been reported by Masaki and coworkers, who examined the behavior of epoxides in the presence of a catalytic amount of the Tt-acid tetracyanoethylene (TCNE, 85) in alcoholic media. First, the oxygen is protonated, creating a good leaving group (step 1 below). The acid-catalyzed epoxide ring-opening reaction mechanism is analogous to the formation of the bromonium ion in halogenation of alkenes and mercurium ion formation in oxymercuration/demercuratioin or alkoxymercuration/demercuration. Like in other S N2 reactions, bimolecular, nucleophilic substitution reactions take place from the backside, resulting in inversion at the electrophilic carbon. This accounts for the observed regiochemical outcome. What about the electrophile? There are two electrophilic carbons in the epoxide, but the best target for the nucleophile in an S N2 reaction is the carbon that is least hindered. When a nucleophilic substitution reaction involves a poor leaving group and a powerful nucleophile, it is very likely to proceed by an S N2 mechanism. The nucleophile itself is a potent, deprotonated, negatively charged methoxide ion. An alkoxide is a poor leaving group, and thus the ring is unlikely to open without a 'push' from the nucleophile. The leaving group is an alkoxide anion, because there is no acid available to protonate the oxygen prior to ring opening. Let us examine the basic, S N2 case first. When an asymmetric epoxide undergoes solvolysis in basic methanol, ring-opening occurs by an S N2 mechanism, and the less substituted carbon is the site of nucleophilic reaction, leading to what we will refer to as product B:Ĭonversely, when solvolysis occurs in acidic methanol, the reaction occurs by a mechanism with substantial S N1 character, and the more substituted carbon is the site of reaction. If the epoxide is asymmetric, the structure of the product will vary according to which mechanism dominates. For the concerted S N2 mechanism, sterics are the dominating consideration. For the S N1 mechanism, the stability of the charged intermediate determines the regioselectivity. Ring-opening reactions can proceed by either S N2 or S N1 mechanisms, depending on the nature of the epoxide and on the reaction conditions. ![]() In a regioselective reaction, two (or more) different constitutional isomers are possible as products, but one is formed preferentially (or sometimes exclusively). ![]() Both mechanisms are good examples of regioselective reactions. The ring-opening reactions of epoxides provide an excellent review of the differences between S N1 and S N2 reactions. S N2, regioselectivity, and stereoselectivity SN2, regioselectivity, and stereoselectivityĮpoxide ring-opening reactions - S N1 vs. Epoxide ring-opening reactions - SN1 vs. |
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